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Metal-organic frameworks (MOFs) with tunable structures and unique host-guest chemistry have emerged as promising candidates for conductive materials. However, the tunability of conductivity and porosity in conductive MOFs and their interrelationship still lack a systematic study. Herein, we report the synthesis of a series of 3D copper MOFs (NU-4000 to NU-4003) using a triphenylene-based hexatopic carboxylate linker. By modulating the ratio of mixed solvents, distinct structural topologies and π-π stacking arrangements were achieved, resulting in electrical conductivity ranging from insulators (˂ 10-6 S/cm) to semiconductors (10-8 ~ 102 S/cm). Among them, NU-4003 features continuous π-π stacking and exhibits a conductivity of 1.7 × 10-6 S/cm. To further enhance conductivity, we encapsulated C60, a strong electron acceptor, within the circular channels of NU-4003, resulting in a remarkable conductivity increase to 140 S/cm with approximately 100% pore occupancy. Even at lower C60 loadings that leave 54% of the pore volume remaining accessible, the conductivity remains exceptionally high at 104 S/cm. This represents an eight-order magnitude enhancement and positions NU-4003-C60 as one of the most conductive 3D MOFs reported to date. This work integrates two charge transport pathways (through-space and electron donor and acceptor) into a single MOF host-guest material, achieving a significant enhancement in conductivity. This study demonstrates the potential of combining host-guest chemistry and π-π stacking to design conductive MOFs with permanent porosity maintained, providing a blueprint for the development of next-generation materials for electronic and energy-related applications. 

Abstract The stellar atmospheric parameters and physical properties of stars in the Kepler Input Catalog (KIC) are of great significance for the study of exoplanets, stellar activity, and asteroseismology. However, despite extensive effort over the past decades, accurate spectroscopic estimates of these parameters are available for only about half of the stars in the full KIC. In our work, by training relationships between photometric colors and spectroscopic stellar parameters from Gaia DR3, the Kepler-INT Survey, Large Sky Area Multi-Object Fiber Spectroscopic Telescope DR10, and Galactic Evolution Experiment at Apache Point Observatory DR17, we have obtained atmospheric parameter estimates for over 195,000 stars, accounting for 97% of the total sample of KIC stars. We obtain 1σuncertainties of 0.1 dex on metallicity [Fe/H], 100 K on effective temperatureT_eff, and 0.2 dex on surface gravity logg. In addition, based on these atmospheric parameters, we estimated the ages, masses, radii, and surface gravities of these stars using the commonly adopted isochrone-fitting approach. External comparisons indicate that the resulting precision for turnoff stars is 20% in age; for dwarf stars, it is 0.07M_⊙in mass, 0.05R_⊙in radius, and 0.12 dex in surface gravity; and for giant stars, it is 0.14M_⊙in mass, 0.73R_⊙in radius, and 0.11 dex in surface gravity.